These Writers Guide's are the result of a collaboration aimed at cataloging canon in the U.N.C.L.E. archives. They haven't been proofread, may not be complete, probably contain errors, and reflect only the opinion and/or mood of the note-taker at the time.
For an overview of U.N.C.L.E. plot and production information, you can't do better than Bill Koenig's Episode Guide .
Paul from Channel D did a week-by-week review of all the episodes. It's located: Here
Paul's been posting fantastic weekly reviews of episodes, as we view them in order, over on Channel D - as far as I know they're not available on the www, but everyone's welcome to come join the party!